Quantum chemical calculations for polymers and organic compounds

The relativistic effects of the orbiting electrons on a model compound were calculated. The computational method used was based on 'Modified Neglect of Differential Overlap' (MNDO). The compound tetracyanoplatinate was used since empirical measurement and calculations along "classical" lines had yielded many known properties. The purpose was to show that for large molecules relativity effects could not be ignored and that these effects could be calculated and yield data in closer agreement to empirical measurements. Both the energy band structure and molecular orbitals are depicted

Fe I line shifts in the optical spectrum of the Sun

New improvements in the measurement of both the optical solar spectrum and laboratory wavelengths for lines of neutral iron are combined to extract central wavelength shifts for 1446 lines observed in the Sun. This provides the largest available database of accurate solar wavelengths useful as a reference for comparison with other solar-type stars. It is shown how the velocity shifts correlate with line strength, approaching a constant value, close to zero, for lines with equivalent widths larger than 200 mA.Comment: Latex file (5 pages), uses l-aa.sty and epsfig.sty (included); 3 Postscript figures, 1 ASCII table, accepted for publication in Astronomy and Astrophysics Supplement Serie

A simple model for the evolution of multi-stranded coronal loops

We develop and analyze a simple cellular automaton (CA) model that reproduces the main properties of the evolution of soft X-ray coronal loops. We are motivated by the observation that these loops evolve in three distinguishable phases that suggest the development, maintainance, and decay of a self-organized system. The model is based on the idea that loops are made of elemental strands that are heated by the relaxation of magnetic stress in the form of nanoflares. In this vision, usually called "the Parker conjecture" (Parker 1988), the origin of stress is the displacement of the strand footpoints due to photospheric convective motions. Modeling the response and evolution of the plasma we obtain synthetic light curves that have the same characteristic properties (intensity, fluctuations, and timescales) as the observed cases. We study the dependence of these properties on the model parameters and find scaling laws that can be used as observational predictions of the model. We discuss the implications of our results for the interpretation of recent loop observations in different wavelengths.Comment: 2010, accepted for publication in Ap